Long-Term Trends in Cloud and Rain Chemistry on Mount Washington, New Hampshire

TitleLong-Term Trends in Cloud and Rain Chemistry on Mount Washington, New Hampshire
Publication TypeJournal Article
Year of Publication2013
AuthorsMurray, GLD, Kimball, KD, L. Hill, B, Hislop, JE, Weathers, KC
JournalWater, Air, & Soil Pollution
Volume224
Issue9
Pagination1 - 14
Date Published2013/09/01/
ISBN Number0049-6979, 1573-2932
KeywordsAcidity, Atmospheric Protection/Air Quality Control/Air Pollution, Clean Air Act Amendments, Climate Change, Cloud and rain water chemistry, Environment, general, Hydrogeology, Montane, Mount Washington NH, Nitrogen, Nocturnal boundary layer, Soil Science & Conservation, Sulfur, Waste Water Technology / Water Pollution Control / Water Management / Aquatic Pollution
Abstract

Growing season rain and cloud events were sampled between 1984–2010 at Lakes of the Clouds (LOC) (1,540 m above sea level (ASL)) which is 1.6 km SW of the summit of Mount Washington, NH (1,914 m ASL). Mount Washington's summit is in the clouds ca. 51 % of the time. All samples were measured for pH, while cations and anions were measured consistently from 1996 to 2010. Annual mean cloud and rain water hydrogen ion concentrations declined significantly from 1984–2010. Nighttime cloud and rain hydrogen, sulfate, ammonium, and nitrate ion concentrations were significantly greater compared to daytime. Ion mean concentrations declined over the 1996–2010 timeframe and more rapidly since 2005. Co-located filter-based aerosol measurement (PM2.5) at LOC had higher ratios of ammonium to sulfate in summer daytime samples post (1995–2010) full implementation of the 1990 Clean Air Act Amendments. This suggests a shift towards more neutralized sulfate aerosol dissolution into clouds with relatively more ammonium and declines in acidity. The origin of cloud water sampled, which ranges from regional fronts to orographic lower elevation air mass uplift, along with the diurnally shifting nocturnal boundary layer that often puts the LOC site in and out of the mixed layer, likely contributes to the diurnal and inter-annual variability observed.

URLhttp://link.springer.com/article/10.1007/s11270-013-1653-7
Short TitleWater Air Soil Pollut